中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines
其他题名: 边臂促进的胺对D-A环丙烷的高对映选择性开环反应及其动力学拆分的研究
作者: Zhou YY(周友运) ; Wang LJ(王丽佳) ; Li J(李军) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 孙秀丽 ; 唐勇
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:22, 页:9066-9069
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A Ni-catalyzed asymmetric ring-opening reaction of 2-substituted cyclopropane-1,1-dicarboxylates with aliphatic amines has been accomplished using the chiral indane-trisoxazoline (In-TOX) ligand. This highly enantioselective reaction provides an efficient approach to a variety of chiral gamma-substituted gamma-amino acid derivatives, which are readily transformed into multifunctionalized piperidines and gamma-lactams. The single-crystal X-ray structure of the TOX-Ni complex is provided, and the role of the side arm in the chiral ligand is discussed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000304837800012
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27973
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2012061.pdf(808KB)----开放获取--View Download

Recommended Citation:
Zhou YY,Wang LJ,Li J,et al. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines[J]. J. Am. Chem. Soc.,2012,134(22):9066-9069.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[周友运]'s Articles
[王丽佳]'s Articles
[李军]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[周友运]‘s Articles
[王丽佳]‘s Articles
[李军]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2012061.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace