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学科主题: 金属有机化学
题名: Organocatalyzed Enantioselective Formal [4+2] Cycloadclition of 2,3-Disubstituted Indole and Methyl Vinyl Ketone
其他题名: 有机催化的2,3-二取代吲哚和甲基乙烯基酮的表观不对称 [4+2] 环加成反应
作者: Cai Q(蔡泉) ; You SL(游书力)
通讯作者: 游书力
刊名: Org. Lett.
发表日期: 2012
卷: 14, 期:12, 页:3040-3043
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A formal [4 + 2] cycloaddition of 2,3-disubstituted indoles with vinyl methyl ketone was realized in the presence of a catalytic amount of quinine-derived primary amine and pentafluorobenzoic acid. This method provides bridged-ring indoline scaffolds containing two quaternary carbon centers with excellent yields and enantioselectivity (up to 98% yield and 98% ee).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000305205300030
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27969
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Cai Q,You SL. Organocatalyzed Enantioselective Formal [4+2] Cycloadclition of 2,3-Disubstituted Indole and Methyl Vinyl Ketone[J]. Org. Lett.,2012,14(12):3040-3043.
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