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学科主题: 金属有机化学
题名: C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride
其他题名: 钇氢化物参与的氧膦C-P及C-H键断裂反应
作者: Lu EL(陆而立) ; Chen YF(陈耀峰) ; Zhou JL(周吉亮) ; Leng XB(冷雪冰)
通讯作者: 陈耀峰
刊名: Organometallics
发表日期: 2012
卷: 31, 期:12, 页:4574-4578
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Reactions of the yttrium anilido hydride [LY(NH(DIPP))(mu-H)](2) (1; L = [MeC(N(DIPP))CHC(Me)(NCH2CH2NMe2)]-, DIPP = (2),6-(Pr2C6H3)-Pr-i)) with three phosphine oxides and two phosphine sulfides are reported. The reaction of 1 with Ph3P=O gives C P bond cleavage and an yttrium anilido phosphinoyl complex, while those with R2MeP=O (R = Me, Ph) result in C H bond cleavage and two yttrium anilido alkyl complexes. 1 also reacted with R3P=S (R = Me, Ph), which demonstrated P S bond cleavage via hydride-based reduction and gave an yttrium anilido sulfide.
语种: 英语
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WOS记录号: WOS:000305588000024
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27959
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lu EL,Chen YF,Zhou JL,et al. C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride[J]. Organometallics,2012,31(12):4574-4578.
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