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学科主题: 金属有机化学
题名: Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution
其他题名: 水溶液中银催化的脂肪酸脱羧氟代
作者: Yin F(尹锋) ; Wang ZT(王振涛) ; Li ZD(李兆栋) ; Li CZ(李超忠)
通讯作者: 李超忠
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:25, 页:10401-10404
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 中国科技大学
英文摘要: Although fluorinated compounds have found widespread applications in the chemical and materials industries, general and site-specific: C(sp(3))-F bond formations are still a challenging task. We report here that with the catalysis of AgNO3, various aliphatic carboxylic acids undergo efficient decarboxylative fluorination with SELECTFLUOR (R) reagent in aqueous solution, leading to the synthesis of the corresponding alkyl fluorides in satisfactory yields under mild conditions. This radical fluorination method is not only efficient and general but also chemoselective and functional-group-compatible, thus making it highly practical in the synthesis of fluorinated molecules. A mechanism involvinig Ag(III)-mediated single electron transfer followed by fluorine atom transfer is proposed for this catalytic fluorodecarboxylation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000305716700024
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27955
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yin F,Wang ZT,Li ZD,et al. Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution[J]. J. Am. Chem. Soc.,2012,134(25):10401-10404.
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