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学科主题: 金属有机化学
题名: Chiral counteranion-directed silver-catalyzed asymmetric synthesis of 1,2-dihydroisoquinolines by Friedel-Crafts alkylation reactions
其他题名: 通过手性抗衡阴离子导向银催化的Friedel-Crafts烷基化反应实现的1,2-二氢异喹啉的不对称合成
作者: Zhang JW(张军伟) ; Xu Z(许喆) ; Gu Q(顾庆) ; Shi XX(施小新) ; Leng XB(冷雪冰) ; You SL(游书力)
通讯作者: 游书力
刊名: Tetrahedron
发表日期: 2012
卷: 68, 期:26, 页:5263-5268
收录类别: SCI
部门归属: 华东理工大学; 中科院上海有机化学研究所
英文摘要: The reaction of ortho-alkynylaryl aldimines and indoles catalyzed by a silver binol-derived phosphate was realized to afford a series of enantioenriched 1,2-dihydroisoquinolines in moderate to good yields and ee. An interesting phenomenon that highly enantioenriched products could be obtained from their lower ee form by silica gel column chromatography was observed, providing an easy access to the enantiopure form of the product. (C) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000305381700023
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27953
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang JW,Xu Z,Gu Q,et al. Chiral counteranion-directed silver-catalyzed asymmetric synthesis of 1,2-dihydroisoquinolines by Friedel-Crafts alkylation reactions[J]. Tetrahedron,2012,68(26):5263-5268.
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