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学科主题: 金属有机化学
题名: Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C-Cl Bonds
其他题名: 从1,2-炔基膦和CuX2出发和成4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides的方法, 以及C-Cl键的Suzuki偶联反应
作者: Xin N(辛宁) ; Ma SM(麻生明)
通讯作者: 麻生明
刊名: Eur. J. Org. Chem.
发表日期: 2012
期: 20, 页:3806-3817
收录类别: SCI
部门归属: 华东师范大学; 中科院上海有机化学研究所
英文摘要: A convenient and efficient synthesis of 4-halo-2,5-dihydro-1,2-oxaphosphole 2-oxides through CuX2-mediated direct halocyclization of diethyl 1,2-allenylphosphonates was developed. The yields range from moderate to excellent. The efficiency of axial-to-central chirality transfer has also been studied. Further Suzuki cross-coupling of the resulting vinylic chlorides with dicyclohexyl(2,4,6-trimethoxyphenyl)phosphane (LB-Phos) as the ligand, was established.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000305942800012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27943
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xin N,Ma SM. Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C-Cl Bonds[J]. Eur. J. Org. Chem.,2012(20):3806-3817.
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