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学科主题: 金属有机化学
题名: Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron
其他题名: 配体控制的高选择性的铜催化的联烯和双(频哪醇)二硼试剂的硼化反应
作者: Yuan WM(袁伟明) ; Ma SM(麻生明)
通讯作者: 麻生明
刊名: Adv. Synth. Catal.
发表日期: 2012
卷: 354, 期:10, 页:1867-1872
收录类别: SCI
部门归属: 华东师范大学; 中科院上海有机化学研究所
英文摘要: Copper-catalyzed highly selective borylcuprations of allenes with bis(pinacolato)diboron produce two different types of alkenylboranes by applying a ligand effect. In the presence of tris(para-methoxyphenyl)phosphine [P(C6H4OMe-p)3], the reaction of aryl-1,2-dienes affords 2-alken-2-yl boronates as the only product with exclusive Z-geometry; the regioselectivity is switched to afford the 1-alken-2-yl boronates as the major products when the bidentate phosphine 2,2'-bis(diphenylphosphino)biphenyl is used as the ligand.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306219000004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27939
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yuan WM,Ma SM. Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron[J]. Adv. Synth. Catal.,2012,354(10):1867-1872.
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