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学科主题: 金属有机化学
题名: Electronic Effect Directed Au(I)-Catalyzed Cyclic C2-H Bond Functionalization of 3-Allenylindoles
其他题名: 电子效应导向的一价金催化3-联烯吲哚C2-H键官能团化的去芳构化反应
作者: Chen B(陈波) ; Fan W(范武) ; Chai GB(柴国碧) ; Ma SM(麻生明)
通讯作者: 麻生明
刊名: Org. Lett.
发表日期: 2012
卷: 14, 期:14, 页:3616-3619
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 华东师范大学
英文摘要: Gold-catalyzed cyclization reactions of indoles with an electron-deficient allene at the 3-position led to formation of dihydrocyclopenta[b]indole derivatives in moderate to excellent yields via C2-H bond functionalization of the indole unit. The presence of the electron-withdrawing alkoxycarbonyl, dialkoxyphosphono, or phenyl is crutial for this transformation. The potential synthetic dihydrocyclopenta[b]indole with the electron-withdrawing group has been demonstrated by applying a [3 + 2] cycloaddition reaction to construct the tretracycloskeleton.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306536500014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27927
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen B,Fan W,Chai GB,et al. Electronic Effect Directed Au(I)-Catalyzed Cyclic C2-H Bond Functionalization of 3-Allenylindoles[J]. Org. Lett.,2012,14(14):3616-3619.
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