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学科主题: 金属有机化学
题名: Palladium-Catalyzed 1,4-Addition of Diarylphosphines to alpha,beta-Unsaturated Aldehydes
其他题名: 钯催化二芳基膦氢对α,β-不饱和烯醛的不对称1,4-加成反应
作者: Chen YR(陈运荣) ; Duan WL(段伟良)
通讯作者: 段伟良
刊名: Org. Lett.
发表日期: 2011-01-01
卷: 13, 期:21, 页:5824-5826
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A highly stereoselective asymmetric 1,4-addition of diarylphosphines to alpha,beta-unsaturated aldehydes catalyzed by a bis(phosphine) pincer-Pd complex has been developed for the synthesis of chiral phosphines with excellent stereoselectivity (up to 98% ee) under mild conditions. The application of the current method to the synthesis of enantiopure bisphosphine and its pincer-Pd complex has also been demonstrated.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000296212200030
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27911
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen YR,Duan WL. Palladium-Catalyzed 1,4-Addition of Diarylphosphines to alpha,beta-Unsaturated Aldehydes[J]. Org. Lett.,2011,13(21):5824-5826.
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