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学科主题: 金属有机化学
题名: Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with alpha-ketones
其他题名: 高效金/银共催化非活化烯烃与酮的连续分子间迈克尔加成/分子内氢烷基化反应
作者: Xiao YP(肖亚平) ; Liu XY(刘心元) ; Zhi ZM(支志明)
通讯作者: 支志明
刊名: Beilstein J. Org. Chem.
发表日期: 2011
卷: 7, 页:1100-1107
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 香港大学
英文摘要: The gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation reaction offers a simple and efficient method for the synthesis of pyrrolidine derivatives in moderate to excellent product yields and with moderate to good diastereoselectivities. The reaction conditions and the substrate scope of this reaction are examined, and a possible mechanism involving AgClO(4) catalyzed intermolecular N-Michael addition and the subsequent gold(I)-catalyzed hydroalkylation is proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000293790300001
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27903
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xiao YP,Liu XY,Zhi ZM. Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with alpha-ketones[J]. Beilstein J. Org. Chem.,2011,7:1100-1107.
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