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学科主题: 金属有机化学
题名: Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins
其他题名: 钯催化的烯烃烯丙位碳氢键官能团化
作者: Liu GS(刘国生) ; Wu YC(吴奕晨)
通讯作者: 刘国生
刊名: Topics in Current Chemistry
发表日期: 2010
卷: 292, 页:195-209
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Transition metal-mediated carbon-hydrogen bond cleavage and functionalization is a mechanistically interesting and synthetically attractive process. One of the important cases is the removal of a allylic hydrogen from an olefin by a Pd-II salt to yield a pi-allylpalladium complex, followed by nucleophilic attack to efficient produce allylic derivatives. In contrast to the well-known allylic acetoxylation of cyclohexene, the reaction of open-chain olefins is fairly poor until recent several years. Some palladium catalytic systems have been reported to achieve allylic C-H functionalization, including acetoxylation, amination and alkylation of terminal alkenes. In the most of cases, ligand is crucial to the success of the transformation. This review surveys the recent development of palladium-catalyzed allylic C-H functionalziation of alkenes. These results promise a significant increase in the scope of olefin transformation.
语种: 英语
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WOS记录号: WOS:000280909300007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27879
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu GS,Wu YC. Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins[J]. Topics in Current Chemistry,2010,292:195-209.
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