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学科主题: 金属有机化学
题名: Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes
其他题名: Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes
作者: Wu T(吴涛) ; Yin GY(阴国印) ; Liu GS(刘国生)
通讯作者: 刘国生
刊名: J. Am. Chem. Soc.
发表日期: 2009
卷: 131, 期:45, 页:16354-16355
收录类别: SCI
部门归属: 上海有机所
英文摘要: A novel palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes has been developed, in which AgF was used as a key fluorinating reagent and PhI(OPiv)(2) as oxidant. The reaction afforded vicinal fluoroamine products with very high regioselectivity. A Pd(II/IV) catalytic cycle was proposed, and preliminary mechanistic studies indicated that direct reductive elimination of Pd(IV) intermediates is favored, albeit competing with S(N)2 nucleophilic attack by fluorine, to form a C-F bond.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000271723000012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27865
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wu T,Yin GY,Liu GS. Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes[J]. J. Am. Chem. Soc.,2009,131(45):16354-16355.
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