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Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand
其他题名Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand
Bie FS(别福升); Li YH(李跃辉); Cao WG(曹卫国); Christian A. Sandoval
2009
发表期刊Chin. J. Chem.
ISSN1001-604X
卷号27期号:12页码:2309-2315
摘要Readily available chiral hybrid NH2/tetrazole ligand [(S)-TEA, 1] in combination with Ru-BINAP or Ru-DIOP complexes catalyzes the asymmetric hydrogenation of a number of simple ketones with moderate enantioselectivity (up to 72% ee). The tetrazole functionality results in reversal of the typically observed chiral-induction for related systems and allows for hydrogenation to be uncharacteristically conducted in (non-protic) THF solvent. The observed catalyst performance is sensitive to the reaction conditions employed and the particular compounds involved. The origins of such features are considered to derive from the added functionality provided by the tetrazole moiety in 1, which due to its modular nature provides a good basis for further development.
学科领域金属有机化学
部门归属上海有机所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000273627600001
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/27791
专题上海有机化学研究所
通讯作者Christian A. Sandoval
推荐引用方式
GB/T 7714
Bie FS,Li YH,Cao WG,et al. Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand[J]. Chin. J. Chem.,2009,27(12):2309-2315.
APA 别福升,李跃辉,曹卫国,&Christian A. Sandoval.(2009).Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand.Chin. J. Chem.,27(12),2309-2315.
MLA 别福升,et al."Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand".Chin. J. Chem. 27.12(2009):2309-2315.
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