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题名: Coupling of FRET and photoinduced electron transfer in regioregular silylene-spaced energy donor-acceptor-electron donor copolymers
其他题名: Coupling of FRET and photoinduced electron transfer in regioregular silylene-spaced energy donor-acceptor-electron donor copolymers
作者: Wang XW(王献文) ; Ye MY(叶美钰) ; Chen ZX(陈志贤) ; LIM TSONGSHIN ; FANN WUNSHAIN ; Lu TY(陆天尧)
通讯作者: 陆天尧
刊名: Macromolecules
发表日期: 2008
卷: 41, 期:8, 页:2762-2770
收录类别: SCI
部门归属: 台湾大学; 上海有机所
英文摘要: Two new silylene-spaced copolymers containing three kinds of different chromophores in regioregular manner were synthesized by rhodium-catalyzed hydrosilylation of a bisalkyne with a bis-silyl hydride. The photophysical and electrochemical properties of these polymers and the corresponding monomeric models were investigated. Time-resolved fluorescence spectroscopy has been employed for detailed kinetic analyses. The chromophores in these polymers have been shown to exhibit light harvesting to collect light energy, energy transfer, and efficient charge separation. The overall efficiencies involving both FRET and PET in these silylene-spaced vinylarene copolymers can be up to 96%.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000255008400003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27719
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Wang XW,Ye MY,Chen ZX,et al. Coupling of FRET and photoinduced electron transfer in regioregular silylene-spaced energy donor-acceptor-electron donor copolymers[J]. Macromolecules,2008,41(8):2762-2770.
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