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A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions
其他题名A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions
CHI MATTHEW KWOKWAI; YU WINGYIU; SO MANHO; ZHOU CONGYING; Deng QH(邓清海); Zhi ZM(支志明)
2008
发表期刊Chem.-Asian J.
ISSN1861-4728
卷号3期号:8-9页码:1256-1265
摘要Ruthenium nanoparticles supported on non-cross-linked soluble polystyrene were prepared by reacting [RuCl2(C6H5CO2Et)](2) with polystyrene in open air. They effectively catalyze intra- and intermolecular carbenoid insertion into C-H and N-H bonds, alkene cyclopropanation, and ammonium ylide/[2,3]-sigmatropic rearrangement reactions. This supported ruthenium catalyst is much more reactive than [RuCl2(p-cymene)](2) and [Ru(Por)CO] for catalytic intermolecular carbenoid C-H bond insertion into saturated alkanes. By using alpha-diazoacetamide as a substrate for intramolecular carbenoid C-H insertion, the supported ruthenium catalyst can be recovered and reused for ten successive iterations without significant loss of activity.
学科领域金属有机化学
部门归属香港大学; 香港理工大学; 上海有机所沪港化学合成联合实验室
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收录类别SCI
语种英语
WOS记录号WOS:000259119400005
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/27705
专题上海有机化学研究所
通讯作者Zhi ZM(支志明)
推荐引用方式
GB/T 7714
CHI MATTHEW KWOKWAI,YU WINGYIU,SO MANHO,et al. A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions[J]. Chem.-Asian J.,2008,3(8-9):1256-1265.
APA CHI MATTHEW KWOKWAI,YU WINGYIU,SO MANHO,ZHOU CONGYING,邓清海,&支志明.(2008).A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions.Chem.-Asian J.,3(8-9),1256-1265.
MLA CHI MATTHEW KWOKWAI,et al."A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions".Chem.-Asian J. 3.8-9(2008):1256-1265.
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