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学科主题: 天然产物有机化学
题名: Stereoselective synthesis of (+/-)-tacamonine
其他题名: Stereoselective synthesis of (+/-)tacamonine
作者: He ZL(何子乐) ; Lin QX(林其先)
通讯作者: 何子乐
刊名: Tetrahedron
发表日期: 2008
卷: 64, 期:45, 页:10401-10405
收录类别: SCI
部门归属: 上海有机所沪港化学合成联合实验室
英文摘要: We report a stereocontrolled approach to the pentacyclic indole alkaloid tacamonine by modifying an earlier route using norbornadiene to supply the nontryptamine portion. By maintaining a bridged system the reduction step of the Bischler-Napieralski reaction proceeded to deliver a bridged diol in which three methine hydrogen atoms are in an all-cis configuration. All 19 skeletal carbon atoms are fully incorporated, therefore, the only remaining steps involved cleavage of the vic-diol subunit in the seven-membered ring and further oxidation and reduction of the resulting lactam alclehyde. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000260290900013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27703
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
He ZL,Lin QX. Stereoselective synthesis of (+/-)-tacamonine[J]. Tetrahedron,2008,64(45):10401-10405.
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