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学科主题: 金属有机化学
题名: Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters
其他题名: Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters
作者: Wan XB(万小兵) ; Sun YH(孙延晖) ; Luo YF(罗云飞) ; Li D(李到) ; Zhang ZG(张兆国)
通讯作者: 张兆国
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:3, 页:1070-1072
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 南京大学
英文摘要: The synthesis and resolution of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed asymmetric hydrogenation reaction of beta-ketoesters are reported. Up to 99.5% ee was achieved. Under solvent-free reaction conditions, acetoacetates could be reduced with good enantioselectivity and high efficiency; a TON of 20 000 was obtained within 3.5 h. The results obtained were comparable to those when SEGPhos was applied.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000226777100045
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27619
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Wan XB,Sun YH,Luo YF,et al. Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters[J]. J. Org. Chem.,2005,70(3):1070-1072.
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