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学科主题: 金属有机化学
题名: Highly selective intra- and intermolecular coupling reactions of diazo compounds to form cis-alkenes using a ruthenium porphyrin catalyst
其他题名: 以钌卟啉为催化剂催化重氢化合物高选择性的偶联形成顺式烯烃的反应
作者: Li GY(李功勇) ; Zhi ZM(支志明)
通讯作者: 支志明
刊名: Org. Lett.
发表日期: 2004
卷: 6, 期:10, 页:1621-1623
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 香港大学
英文摘要: [Ru(2,6-Cl2TPP)(CO)] catalyzed intramolecular coupling reactions of bisdiazoacetates and intermolecular coupling reactions of monodiazoacetates to afford the coupling products in up to 76% and 93% yields, respectively. Only the cis isomers were obtained from the reactions. Employing such a ruthenium-catalyzed coupling reaction of a diazo compound as a key step allowed the synthesis of Patulolide B in 67% yield with a ratio of >40:1 against its trans isomer.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000221278500026
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27587
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Li GY,Zhi ZM. Highly selective intra- and intermolecular coupling reactions of diazo compounds to form cis-alkenes using a ruthenium porphyrin catalyst[J]. Org. Lett.,2004,6(10):1621-1623.
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