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学科主题: 金属有机化学
题名: Steoselective synthesis of functionalized pyrrolidines by ruthenium porphyrin-catalyzed decomposition of α -diazo esters and cascade azomethine ylide formation/1,3-dipolar cycloaddition reactions
其他题名: 钌卟啉催化重氮化合物形成亚胺叶立德和1,3-偶极环加成串联反应立体选择性合成官能团化的吡咯环
作者: Li GY(李功勇) ; Chen J(陈建) ; Yu YY(余永耀) ; Hong W(洪炜) ; Zhi ZM(支志明)
通讯作者: 支志明
刊名: Org. Lett.
发表日期: 2003-01-01
卷: 5, 期:12, 页:2153-2156
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所 沪港化学合成联合实验室; 香港中文大学生物化学系
英文摘要: Ruthenium porphyrins catalyze three-component coupling reaction of α-diazo esters with a series of N-benzylidene imines and alkenes to form functionalized pyrrolidines in excellent diastereoselectivities. The reaction proceeds via a reactive ruthenium-carbene intermediate and its subsequent reaction with imine to generate azomethine ylide, which reacts with alkenes via 1,3-diloar cycloaddition
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27569
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Li GY,Chen J,Yu YY,et al. Steoselective synthesis of functionalized pyrrolidines by ruthenium porphyrin-catalyzed decomposition of α -diazo esters and cascade azomethine ylide formation/1,3-dipolar cycloaddition reactions[J]. Org. Lett.,2003,5(12):2153-2156.
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