SIOC OpenIR  > 上海有机化学研究所
Synthesis, resolution, and applications of 1.16-dihydroxytetraphenylene as a novel building block in molecular recognition and assembly
其他题名1,16-二羟基四苯并环辛四烯的合成拆分,以及作为新型合成砌块在分子识别和分子组装中的应用
Wen JF(温剑锋); Hong W(洪炜); Yuan K(苑可); Mai SW(麦松威); Huang NZ(黄乃正)
2003
发表期刊J. Org. Chem.
ISSN0022-3263
卷号68期号:23页码:8918-8931
摘要This paper concerns the synthesis of l .16-dihydrorytetraphenylene (DHTP) (2) by employing a novel NBS bromination route. T±=)-DHTP 2 was successfully resolved into its optical antipodes and converted to (±=)-l . 16-bis(diphenylphosphino)tetraphenylene (BPTP) (26) . Whose platinum complex BPTP-PtClz (27) was also obtained. As a hydrogen bond donor. Racemic and optically active DHTP 2 was allowed to assemble with 4.4'-bipyridine to form single crystals of good quality. X-ray Diffraction studies of these crystals revealed that the crystallographic packing of the hydrogen bonded complex between (±=)-2 and 4.4'-bipyridine was different from the one formed from (S-2 and 4,4'-bipyridine. It was found that an infinite zigzag chain with alternate chirality was formed in the assembly of (d=)-2 and 4.4'-bipyridine, while (S-2 and 4.4'-bipyridine failed to show the same assembly pattern. The reason (±=)-2 formed an alternate and zigzag chain with 4,4'-bipyridine was most likely due to the inherent stability of this supramolecular assembly. The chiral recognition between 2 and optically active BINAP under the direction of platinum(II) has also been examined. IH and 31p NMR spectroscopic studies demonstrated that there was an obvious discrimination of 2 between the enantiomers of BINAP-PtCO^3
学科领域有机化学
部门归属中国科学院上海有机化学研究所 沪港化学合成联合实验室; 香港中文大学生物化学系
URL查看原文
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/27551
专题上海有机化学研究所
通讯作者Huang NZ(黄乃正)
推荐引用方式
GB/T 7714
Wen JF,Hong W,Yuan K,et al. Synthesis, resolution, and applications of 1.16-dihydroxytetraphenylene as a novel building block in molecular recognition and assembly[J]. J. Org. Chem.,2003,68(23):8918-8931.
APA 温剑锋,洪炜,苑可,麦松威,&黄乃正.(2003).Synthesis, resolution, and applications of 1.16-dihydroxytetraphenylene as a novel building block in molecular recognition and assembly.J. Org. Chem.,68(23),8918-8931.
MLA 温剑锋,et al."Synthesis, resolution, and applications of 1.16-dihydroxytetraphenylene as a novel building block in molecular recognition and assembly".J. Org. Chem. 68.23(2003):8918-8931.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2003240.pdf(528KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[温剑锋]的文章
[洪炜]的文章
[苑可]的文章
百度学术
百度学术中相似的文章
[温剑锋]的文章
[洪炜]的文章
[苑可]的文章
必应学术
必应学术中相似的文章
[温剑锋]的文章
[洪炜]的文章
[苑可]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。