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学科主题: 有机化学
题名: 6α-取代的(1S,7aS)-(+)-1-叔丁氧基-7a-甲基-2,3,5,6,7,7a-六氢茚-5-酮的合成
其他题名: SYNTHESIS OF 6-ALPHA-SUBSTITUTED(1S, 7AS)-(+)-1-TERT-BUTOXY-7A-METHYL-2, 3, 5, 6, 7, 7A-HEXAHYDROINDEN-5-ONES
作者: 孙琳 ; 熊意风 ; 伍建华 ; 蔡祖恽
通讯作者: 蔡祖恽
刊名: 化学学报
发表日期: 1991-01-01T00:00:00Z
卷: 49, 期:4, 页:406-411
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: It is known that 11-C-substituted steroids usually possess much higher biological activities than their mother substances. In this paper six 6-alpha-substituted (1S, 7-alpha-S)-(+)-1-t-butoxy-7a-methyl-2, 3, 5, 6, 7, 7a-hexahydroinden-5-ones(4, 6, 7, 8, 9, 11) were synthesized in good yields with high stereoselectivity. These compounds are good intermediates for the syntheses of the related 11-C-substituted steroids.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27225
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
孙琳,熊意风,伍建华,等. 6α-取代的(1S,7aS)-(+)-1-叔丁氧基-7a-甲基-2,3,5,6,7,7a-六氢茚-5-酮的合成[J]. 化学学报,1991,49(4):406-411.
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