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学科主题: 天然产物有机化学
题名: Facile construction of the pentacyclic framework of subincanadine B. Synthesis of 20-deethylenylated subincanadine B and 19,20-dihydrosubincanadine B
其他题名: Facile construction of the pentacyclic framework of subincanadine B. Synthesis of 20-deethylenylated subincanadine B and 19,20-dihydrosubincanadine B
作者: LIU YANQIN ; Luo SJ(罗盛军) ; FU XINGNIAN ; Fang F(方芳) ; ZHUANG ZEYANG ; Xiong WT(熊婉婷) ; Jia XS(贾学顺) ; Zhai HB(翟宏斌)
通讯作者: 翟宏斌
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:1, 页:115-118
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 上海大学
英文摘要: We describe a facile approach for effectively constructing the pentacyclic framework of subincanadine B. The seven-step assembly of tetracyclic ketone 14 featured Michael addition, Pictet-Spengler cyclization, and Dieckmann condensation. From this key ketone intermediate, two analogues of subincanadine 13, i.e., 20-deethylenylated subincanadine B (27) and 19,20-dihydrosubincanadine B (31), were synthesized in four steps, respectively.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000234391600030
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25589
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
LIU YANQIN,Luo SJ,FU XINGNIAN,et al. Facile construction of the pentacyclic framework of subincanadine B. Synthesis of 20-deethylenylated subincanadine B and 19,20-dihydrosubincanadine B[J]. Org. Lett.,2006,8(1):115-118.
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