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学科主题: 天然产物有机化学
题名: A facile asymmetric route to (-)-aphanorphine
其他题名: (-)-Aphanorphine不对称合成的一种简洁路线
作者: Zhai HB(翟宏斌) ; Luo SJ(罗盛军) ; Ye CF(叶承峰) ; Ma YX(马永祥)
通讯作者: 翟宏斌
刊名: J. Org. Chem.
发表日期: 2003
卷: 68, 期:21, 页:8268-8271
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机化学实验室; 兰州大学化学系
英文摘要: 8 O-Methylaphanorphine was synthesized from 4-methoxyphenylacetaldehyde in 36% overall yield and in nine steps, featuring the formation of ring B via a Friedel-Crafts alkylative cyclization with the concomitant stereospecific introduction of the benzylic quaternary carbon center, The current work constitutes an efficient enantioselective formal synthesis of 3-benzazepine marine alkaloid (-)-aphanorphine.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000185907100050
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25571
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Zhai HB,Luo SJ,Ye CF,et al. A facile asymmetric route to (-)-aphanorphine[J]. J. Org. Chem.,2003,68(21):8268-8271.
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