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学科主题: 天然产物有机化学
题名: Novel total syntheses of (±)-oxerine by intramolecular heck reaction
其他题名: 应用分子内Heck 反应对(±)Oxerine 的全合成
作者: Zhao JR(赵景瑞) ; Yang XX(杨晓霞) ; Jia XS(贾学顺) ; Luo SJ(罗盛军) ; Zhai HB(翟宏斌)
通讯作者: 翟宏斌
刊名: Tetrahedron
发表日期: 2003-01-01
卷: 59, 期:47, 页:9379-9382
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机化学实验室; 上海大学化学系
英文摘要: Both a three-step and a five-step syntheses ofmonoterpene alkaloid(±)-oxerine from alcohol 6 have been accomplished. In the second approach, the synthetic efficiency was enhanced by implementing a one-pot protocol (deprotonation/silylation/alkylation/desilylation).The construction of the cyclopental[c]pyridine framework was realized by an intramolecular Heck reaction, which should be adaptabel for the synthesis of other related monoterpene pyridine alkaloids.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25565
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Zhao JR,Yang XX,Jia XS,et al. Novel total syntheses of (±)-oxerine by intramolecular heck reaction[J]. Tetrahedron,2003,59(47):9379-9382.
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