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学科主题: 高分子化学
题名: A New Titanium (IV) Complex Bearing Phenoxyimine-Fluorene Ligand and Its Use as Catalyst for Ethylene Homo- and Copolymerization
其他题名: 一种含有水杨醛亚胺-芴基配体的新型钛配合物及其在催化乙烯均聚和共聚中的应用
作者: Zhong L(钟良) ; Cui K(崔崑) ; Xie P(谢鹏) ; Chen JZ(陈健壮) ; Ma Z(马志)
通讯作者: 马志
刊名: J. Polym. Sci. Pol. Chem.
发表日期: 2010
卷: 48, 期:7, 页:1617-1621
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: A new titanium (IV) complex bearing phenoxyimine-fluorene ligand was prepared and its behaviors in ethylene homo- and copolymerization with 1-hexene, 1-octene, and norbomene in the presence of modified methylaluminoxane (MMAO) were studied respectively. The effects of various polymerization conditions including polymerization temperature, ethylene pressure and the concentration of comonomer on the catalytic activities and properties of the resultant polymer were investigated. The broad molecular weight distribution of resulting polymer indicated that the multiple active species were formed during polymerization. Such complex showed good catalytic activities in ethylene homo- and copolymerizations and good capabilities of incorporating various comonomers into polyethylene backbone. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1617-1621, 2010
语种: 英语
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WOS记录号: WOS:000275848000017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25389
Appears in Collections:分析化学研究室_期刊论文

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Recommended Citation:
Zhong L,Cui K,Xie P,et al. A New Titanium (IV) Complex Bearing Phenoxyimine-Fluorene Ligand and Its Use as Catalyst for Ethylene Homo- and Copolymerization[J]. J. Polym. Sci. Pol. Chem.,2010,48(7):1617-1621.
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