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学科主题: 高分子化学
题名: Highly ordered microporous films containing a polyolefin segment fabricated by the breath-figure method using well-defined polymethylene-b-polystyrene copolymers
其他题名: 利用呼吸图法和结构可控的聚亚甲基-b-聚苯乙烯嵌段共聚物制备的含有聚烯烃链段的高度有序微孔薄膜
作者: Li J(李剑) ; Zhao QL(赵巧玲) ; Chen JZ(陈健壮) ; Li L(李磊) ; Huang J(黄晋) ; Ma Z(马志) ; Zhong YW(钟雅文)
通讯作者: 李磊 ; 马志
刊名: Polym. Chem.
发表日期: 2010
卷: 1, 期:2, 页:164-167
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 厦门大学
英文摘要: Highly ordered microporous films containing polyolefin segment were successfully fabricated via the breath-figure (BF) method using well-defined polymethylene-h-polystyrene (PM-h-PS) diblock copolymers in CS2 under a static humid condition. The effects of molecular weight of diblock copolymers, relative humid, fabrication method and temperature on the morphology of film are investigated. The honeycomb porous films with different pore size (1.2-2.5 mu m) were obtained by using PM-h-PS with different PM : PS ratio. The thick (7 mu m) and thin (2 mu m) films were fabricated via a different process. The film with a pothole-like structure was fabricated when using PM-h-PS with the shortest PS segment. Smaller satellite pores were found to surround the regular micropores of honeycomb films when the BF process was carried out at 28 degrees C.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000278602700006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25385
Appears in Collections:分析化学研究室_期刊论文

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Recommended Citation:
Li J,Zhao QL,Chen JZ,et al. Highly ordered microporous films containing a polyolefin segment fabricated by the breath-figure method using well-defined polymethylene-b-polystyrene copolymers[J]. Polym. Chem.,2010,1(2):164-167.
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