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学科主题: 金属有机化学
题名: Neodymium(III) phosphinidene complexes supported by pentamethylcyclopentadienyl and hydrotris(pyrazolyl)borate ligands
其他题名: 基于五甲基环戊二烯基和氢化三吡唑基硼酸盐配体的钕(III)的膦卡宾化合物
作者: Cui P(崔鹏) ; Chen YF(陈耀峰) ; BORZOV MAXIM V
通讯作者: 陈耀峰
刊名: Dalton Trans.
发表日期: 2010
卷: 39, 期:29, 页:6886-6890
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 西北大学
英文摘要: Synthesis of new neodymium(III) phosphinidene complexes from a neodymium(III) phosphinidene iodide [(mu-PC6H3-2,6-Pr-i(2))Nd(I)(THF)(3)](2) (1) was studied. The metathesis reaction of 1 with KC5Me5 (KCp*) gave a neodymium(III) pentamethylcyclopentadienyl phosphinidene complex [(mu-PC6H3-2,6-Pr-i(2))(C5Me5)Nd(THF)](2) (2), and that with potassium hydrotris(pyrazolyl)borate KHB(3-phenylpz)(3) (KTp(Ph)) generated a neodymium(III) hydrotris(pyrazolyl)borate phosphinidene complex [(mu-PC6H3-2,6-Pr-i(2))(Tp(Ph)*)Nd(THF)](2) (3) and a C-H bond activation byproduct [kappa 4(N,N',N '',C-Ph)-Tp(Ph)]Tp(Ph)Nd (4). Complexes 2-4 have been characterized by single-crystal X-ray diffraction analysis.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000279913100042
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25325
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Cui P,Chen YF,BORZOV MAXIM V. Neodymium(III) phosphinidene complexes supported by pentamethylcyclopentadienyl and hydrotris(pyrazolyl)borate ligands[J]. Dalton Trans.,2010,39(29):6886-6890.
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