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学科主题: 金属有机化学
题名: Synthesis and molecular structure of a tetrameric neodymium-silsesquioxane cage complex: {[(i-C4H9)(7)(Si7O12) Nd](4)NaCl}
其他题名: Synthesis and molecular structure of a tetrameric neodymium-silsesquioxane cage complex: {[(i-C4H9)(7)(Si7O12) Nd](4)NaCl}
作者: Wu GM(吴光明) ; Chen YF(陈耀峰) ; Xu DJ(徐端均) ; Liu JC(刘家楚) ; Sun WL(孙维林) ; Shen ZQ(沈之荃)
通讯作者: 孙维林 ; 沈之荃
刊名: J. Organomet. Chem.
发表日期: 2009-01-01
卷: 694, 期:9-10, 页:1571-1574
收录类别: SCI
部门归属: 浙江大学; 上海有机所
英文摘要: A new tetrameric neodymium-silsesquioxane cage complex {[(i-C4H9)(7)(Si7O12)Nd](4)NaCl} (1) was prepared by the reaction of NdCl3 with i-PrONa, and subsequent treatment with trisilanol [(i-C4H9)(7) (Si7O9)(OH)(3)] in toluene. The molecular structure of the complex was determined by single crystal X-ray diffraction. Preliminary study shows that complex 1 is active for highly cis-1,4 polymerization of isoprene (92% selectivity) in the presence of AlEt3 and Me3SiCl. (C) 2009 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25321
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wu GM,Chen YF,Xu DJ,et al. Synthesis and molecular structure of a tetrameric neodymium-silsesquioxane cage complex: {[(i-C4H9)(7)(Si7O12) Nd](4)NaCl}[J]. J. Organomet. Chem.,2009,694(9-10):1571-1574.
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