中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Monoalkyllanthanide Complexes with New beta-Diketiminato Derivative Dianionic Ligands
其他题名: Monoalkyllanthanide Complexes with New beta-Diketiminato Derivative Dianionic Ligands
作者: Lu EL(陆而立) ; Gan W(甘伟) ; Chen YF(陈耀峰)
通讯作者: 陈耀峰
刊名: Organometallics
发表日期: 2009
卷: 28, 期:7, 页:2318-2324
收录类别: SCI
部门归属: 上海有机所; 西北大学
英文摘要: A new class of beta-diketiminato derivative dianionic ligands was designed, and three ligand precursors [CH3C(ArNH)CHC(CH3)(NCH2CH2-NHR)] (Ar = 2,6-(Pr-i)(2)C6H3; R = Bu-t (H2M), 2,6-(CH3)(2)C6H3 (H(2)L2), 2,6-(Pr-i)(2)C6H3 (H(2)L3)) were synthesized. The alkane elimination reactions between these ligand precursors and Ln(CH2SiMe3)(3)(THF)(n) provided eight five-coordinate monoalkyllanthanide complexes, in which the ligand serves as a tridentate dianionic donor, with one -CH2SiMe3 and one THF molecule completing the five-coordinate center. These monoalkyl complexes exhibited low to very high catalytic activities for intramolecular hydroamination of 2,2-dimethyl-1-aminopent-4-ene. The catalytic activity increased with increasing metal ion size. For the Nd complex, 98% yield was obtained in 1 h at 60 degrees C with 0.5 mol % catalyst loading.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264932700045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25319
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2009342.pdf(536KB)----开放获取--View Download

Recommended Citation:
Lu EL,Gan W,Chen YF. Monoalkyllanthanide Complexes with New beta-Diketiminato Derivative Dianionic Ligands[J]. Organometallics,2009,28(7):2318-2324.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[陆而立]'s Articles
[甘伟]'s Articles
[陈耀峰]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[陆而立]‘s Articles
[甘伟]‘s Articles
[陈耀峰]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2009342.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace