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学科主题: 氟化学 ; 金属有机化学
题名: Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts
其他题名: 铜粉促进的三氟甲基锍盐与芳基硼酸的三氟甲基化
作者: Zhang CP(张成潘) ; Cai J(蔡吉) ; Zhou CB(周昌兵) ; Wang XP(王小平) ; Zheng X(郑兴) ; Gu YC(顾玉诚) ; Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chem. Commun.
发表日期: 2011
卷: 47, 期:33, 页:9516-9518
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 南华大学; 先正达公司
英文摘要: The ligand-free trifluoromethylation of arylboronic acids with a [Ph(2)SCF(3)](+)[OTf](-)/Cu(0) system has been carefully investigated. Aryl-, alkenyl- and heteroarylboronic acids with a variety of functional groups were suitable substrates for this reaction. It is suggested that a CuCF(3) species is formed under the reaction conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000293648200072
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25245
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang CP,Cai J,Zhou CB,et al. Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts[J]. Chem. Commun.,2011,47(33):9516-9518.
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