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学科主题: 氟化学
题名: The chemical transformation of beta-bromodifluoromethyl beta-enaminoketones: Synthesis of difluoromethylene thioether compounds 2-bromodifluoromethyl-quinoline; difluoromethylene thioether; gem-difluorinated quinolines; thiophenols; cyclization; nucleophilic substitution
其他题名: β-溴二氟甲基β-烯氨酮的化学转化
作者: Wu YM(吴永明) ; Li Y(李亚) ; Deng J(邓娟)
通讯作者: 吴永明
刊名: J. Fluor. Chem.
发表日期: 2006-01-01
卷: 127, 期:2, 页:223-228
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A series of 2-bromodifluoromethylquinoline derivatives were synthesized by cyclization of beta-bromodifluoromethyl beta-enaminoketones catalyzed by polyphosphoric acid. Difluoromethylene thioether or ether derivatives of quinoline and but-2-en-1-one were obtained by the subustitute reaction of CF2Br with thio- and oxygen nucleophiles. (c) 2005 Published by Elsevier B.V.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/25133
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Wu YM,Li Y,Deng J. The chemical transformation of beta-bromodifluoromethyl beta-enaminoketones: Synthesis of difluoromethylene thioether compounds 2-bromodifluoromethyl-quinoline; difluoromethylene thioether; gem-difluorinated quinolines; thiophenols; cyclization; nucleophilic substitution[J]. J. Fluor. Chem.,2006,127(2):223-228.
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