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学科主题: 元素有机化学
题名: The novel syntheses of α-frifluoromethylated ketones form β-bromoenol phosphates
其他题名: 从β溴代醇磷酸酯合成α-三氟甲基酮的新方法
作者: Huang XG(黄小根) ; He YT(何艳涛) ; Ding YX(丁贻祥)
通讯作者: 丁贻祥
刊名: Phosphorus Sulfur Silicon Relat. Elem.
发表日期: 2001-01-01
卷: 174, 页:201-207
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机化学实验室
英文摘要: A series of 1-aryl-3,3,3-trifluro-1-propanones have been synthesized from the reaction of FO^2SCF^2CO^2Me with β-bromoenol phosphates in the presence of Cul in moderate yield. The reaction mechanism was discussion. The electron-withdrawing substituent at the β-position of the enol phosphates promoted the catalytic cleavage of the O-P bond in enol phosphates by fluoride ion.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24643
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Huang XG,He YT,Ding YX. The novel syntheses of α-frifluoromethylated ketones form β-bromoenol phosphates[J]. Phosphorus Sulfur Silicon Relat. Elem.,2001,174:201-207.
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