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学科主题: 高分子化学 ; 氟化学
题名: Effects of ethylene oxide spacer length on solution properties of water-soluble flurorocarbon-containing hydrophobically associating poly(acrylic acid-coRf-PEG macromonomer)
其他题名: 氧乙烯基继长度对水溶性含氟碳疏水缔合型聚丙烯酚Rf-PEG大分子共聚物溶液性质的影响
作者: Du LB(杜立斌) ; Zhuang DQ(庄东青) ; Liu SP(刘寿平) ; Zhang YX(章云祥)
通讯作者: 章云祥
刊名: Chin. J. Chem.
发表日期: 2003-01-01T00:00:00Z
卷: 21, 期:6, 页:698-705
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所高分子材料研究室
英文摘要: Poly(acrylic acid)s (PPAs)modified with a series of fluorocarbon group (Rf) end-capped poly(ethylene glycol)(PEG) macromonomers (number of ethylene oxide unit: 1,9,23,45) and corresponding copolymers without fluorocarbon end groups were synthesized. It was found that the effect of the hydrophobic association of fluorocarbon groups on the solution viscosity prevailed over that of the hydrogen bond between grafted PEG and the backbone. Rheological measurement on the aqueous solutions of these poly(acrylic acid-coRf-PEG macromonomer) s demonstrated that the best thickening performance wasshown when the number of ethylene oxide unit (EO number) was 23.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24527
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Du LB,Zhuang DQ,Liu SP,et al. Effects of ethylene oxide spacer length on solution properties of water-soluble flurorocarbon-containing hydrophobically associating poly(acrylic acid-coRf-PEG macromonomer)[J]. Chin. J. Chem.,2003,21(6):698-705.
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