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学科主题: 高分子化学 ; 氟化学
题名: Synthesis and characterization of fluorocarbon-containing, hydrophobically associative poly(acrylic acid-co-Rf-poly(ethylene glycol) macromonomer)
其他题名: 包含氟碳的疏水碲合的聚丙烯酸与聚乙二醇的大分子单体共聚物的合成与表征
作者: Zhang YX(章云祥) ; SHOUPING LIU ; LIBIN DU ; Zhuang DQ(庄东青) ; JUNYAN CHEN ; MING JIANG ; E. HOGEN-ESCH ; SHUGUANG WU ; GRAHAM SWIFT
通讯作者: 章云祥
刊名: J. Appl. Polym. Sci.
发表日期: 2002-01-01
卷: 84, 期:5, 页:1035-1047
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所高分子材料研究室; 复旦大学高分子科学与工程; 南加州大学Loker碳氢研究所; Rohm & Hass 公司研发部
英文摘要: Fluorocarbon-or hydrocarbon-end-capped poly(ethylene glycol)(PEG) macromonomers were prepared with coupling methods. Several factors affecting the synthesis were studied, and the optimal condition was ascertained. The critical micelle concentrations of these macromonomers were determined with the fluorescence method. Novel fluorocarbon-containing, hydrophobically modified, alkali-soluble copolymers were made by the copolymerization of fluorocarbon0or hydrocarbon-alkyl-end-capped PEG macromonomers with acrylic acid in an organic solvent. The effects of the macromonomer contents, polymerization conditions, spacer, temperature, shear rate, pH, and addition of salt and various surfactants on the solution viscosity were preliminarily investigated. A very strong hydrophobic association was found for these copolymer solutions.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24519
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Zhang YX,SHOUPING LIU,LIBIN DU,et al. Synthesis and characterization of fluorocarbon-containing, hydrophobically associative poly(acrylic acid-co-Rf-poly(ethylene glycol) macromonomer)[J]. J. Appl. Polym. Sci.,2002,84(5):1035-1047.
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