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Fluorocarbon-containing hydrophobically modified poly(N-isopropylacrylamide)
Alternative Title氟碳基团疏水改性的聚N-异丙基烯酰胺
Zhang YX(章云祥); Fang Q(方勤); Fu YQ(府宇清); Da AH(达爱华)
1999
Source PublicationChin. J. Chem.
ISSN1001-604X
Volume17Issue:3Pages:244-257 17(3) 0244-0257 (1999)
Abstractfluorocarbon-modified poly(N_isopropylacrylamide) has been synthesizedby copolymerization of N-isopropyl acrylamide with a small amount of acrylateor methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is strongerthan that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content (>2.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol%) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding NaCl and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbons.
Subject Area高分子化学 ; 氟化学
Department中国科学院上海有机化学研究所高分子材料研究室
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Indexed BySCI
Language英语
WOS IDWOS:000080470100006
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/24479
Collection高分子材料研究室
Corresponding AuthorZhang YX(章云祥)
Recommended Citation
GB/T 7714
Zhang YX,Fang Q,Fu YQ,et al. Fluorocarbon-containing hydrophobically modified poly(N-isopropylacrylamide)[J]. Chin. J. Chem.,1999,17(3):244-257 17(3) 0244-0257 (1999).
APA 章云祥,方勤,府宇清,&达爱华.(1999).Fluorocarbon-containing hydrophobically modified poly(N-isopropylacrylamide).Chin. J. Chem.,17(3),244-257 17(3) 0244-0257 (1999).
MLA 章云祥,et al."Fluorocarbon-containing hydrophobically modified poly(N-isopropylacrylamide)".Chin. J. Chem. 17.3(1999):244-257 17(3) 0244-0257 (1999).
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