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学科主题: 高分子化学
题名: 2-甲基-2-丁烯二酸单甲酯的合成及其与丙烯腈二元共聚的表观竞聚率的测定
其他题名: Synthesis of (Z)-2-methyl-2-butenedioic acid-1-methyl ester and determination of apparent reactivity ratio of copolymerization with acrylonitrile
作者: 杨俊锋 ; 陆国林 ; 谭久青 ; 黄晓宇 ; 陈惠芳 ; 潘鼎
通讯作者: 陆国林 ; 潘鼎
刊名: 化学学报
发表日期: 2008-01-01
卷: 66, 期:14, 页:1753-1757
收录类别: SCI
部门归属: 上海有机化学研究所; 杭州大学
英文摘要: A new methacrylate monomer, (Z)-2-methyl-2-butenedioic acid-1-methyl ester (MBAME), was synthesized using citraconic anhydride as starting material. This monomer can copolymerize with acrylonitrile in N,N-dimethylformamide at 70 degrees C using 2,2'-azobisisobutyronitrile as initiator. The apparent reactivity ratio of AN/MBAME copolymerization system calculated by Fineman-Ross method was 7.985 for AN and 0.599 for MBAME, respectively. This result may benefit the production of PAN-based carbon fiber.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24389
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
杨俊锋,陆国林,谭久青,等. 2-甲基-2-丁烯二酸单甲酯的合成及其与丙烯腈二元共聚的表观竞聚率的测定[J]. 化学学报,2008,66(14):1753-1757.
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