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学科主题: 高分子化学
题名: Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene
其他题名: 以6-甲基-1,2-庚二烯-4-醇和苯乙烯为单体合成聚联烯主链的接枝共聚物
作者: Zhang XH(张晓环) ; Shen Z(沈重) ; Li LT(李利涛) ; Zhang S(张森) ; Lu GL(陆国林) ; Huang XY(黄晓宇)
通讯作者: 黄晓宇
刊名: J. Polym. Sci. Pol. Chem.
发表日期: 2007
卷: 45, 期:23, 页:5509-5517
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: A series of well-defined graft copolymers with a polyallene-based backbone and polystyrene side chains were synthesized by the combination of living coordination polymerization of 6-methyl-1,2-heptadien-4-ol and atom transfer radical polymerization (ATRP) of styrene. Poly(alcohol) with polyallene repeating units were prepared via 6-methyl-1,2-heptadien-4-ol by living coordination polymerization initiated by [(eta(3)-allyl)NiOCOCF3](2) firstly, followed by transforming the pendant hydroxyl groups into halogen-containing ATRP initiation groups. Grafting-from route was employed in the following step for the synthesis of the well-defined graft copolymer: polystyrene was grafted to the backbone via ATRP of styrene. The cleaved polystyrene side chains show a narrow molecular weight distribution (M-w/M-n = 1.06). This kind of graft copolymer is the first example of graft copolymer via allene derivative and styrenic monomer. ? 2007 Wiley Periodicals, Inc.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000251631100014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24383
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Zhang XH,Shen Z,Li LT,et al. Synthesis of polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and styrene[J]. J. Polym. Sci. Pol. Chem.,2007,45(23):5509-5517.
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