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学科主题: 高分子化学
题名: A starlike Amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbones and hydrophobic polystyrene side chains
其他题名: 含有亲水聚丙烯酸主链和憎水聚苯乙烯侧链的两亲性星型接枝共聚物
作者: Peng D(彭丹) ; Feng C(冯纯) ; Lu GL(陆国林) ; Zhang S(张森) ; Zhang XH(张晓环) ; Huang XY(黄晓宇)
通讯作者: 黄晓宇
刊名: J. Polym. Sci. Pol. Chem.
发表日期: 2007
卷: 45, 期:16, 页:3687-3697
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: A well-defined starlike amphiphilic graft copolymer bearing hydrophilic poly(acrylic acid) backbones and hydrophobic polystyrene side chains was synthesized by successive atom transfer radical polymerization followed by the hydrolysis of poly(methoxymethyl acrylate) backbone. A grafting-from strategy was employed for the synthesis of a graft copolymer with narrow molecular weight distribution. Hydrophobic polystyrene side chains were connected to the backbones through stable C-C bonds. The poly(methoxymethyl acrylate) backbones can be easily hydrolyzed with HCl without affecting the hydrophobic polystyrene side chains. This kind of amphiphilic graft copolymer can form stable sphere micelles in water. The sizes of the micelles were dependent on the ionic strength and pH value. (C) 2007 Wiley Periodicals, Inc.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000248354900021
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24379
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Peng D,Feng C,Lu GL,et al. A starlike Amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbones and hydrophobic polystyrene side chains[J]. J. Polym. Sci. Pol. Chem.,2007,45(16):3687-3697.
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