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学科主题: 高分子化学
题名: Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains
其他题名: 含有亲水聚丙烯酸主链和憎水聚苯乙烯侧链的两亲性接枝共聚物的合成
作者: Peng D(彭丹) ; Zhang XH(张晓环) ; Huang XY(黄晓宇)
通讯作者: 黄晓宇
刊名: Polymer
发表日期: 2006
卷: 47, 期:17, 页:6072-6080
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: A series of well-defined amphiphilic graft copolymers consisting hydrophilic poly(acrylic acid) backbones and hydrophobic polystyrene side chains were synthesized by successive atom transfer radical polymerization (ATRP) followed by hydrolysis of poly(methoxymethyl acrylate) (PMOMA) backbone. Grafting-from strategy was employed for the synthesis of graft copolymers with narrow molecular weight distribution. Hydrophobic side chains were connected to the backbone through stable C-C bonds. The backbone can be easily hydrolyzed with HCl without affecting hydrophobic side chains. This family of amphiphilic graft copolymers can form stable micelles in water. The critical micelle concentration was determined by fluorescence spectroscopy. The micellar morphologies and sizes were studied using transmission electron microscopy (TEM) and dynamic light scattering (DLS). The sizes of micelles were dependent on ionic strength, pH value and preparation conditions. (c) 2006 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000239973500008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24365
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Peng D,Zhang XH,Huang XY. Synthesis of amphiphilic graft copolymer with hydrophilic poly(acrylic acid) backbone and hydrophobic polystyrene side chains[J]. Polymer,2006,47(17):6072-6080.
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