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学科主题: 天然产物有机化学
题名: Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization
其他题名: 以扭曲肉芝甲酯亲双烯体的合成研究第二部分:二碘化钐参与的14元碳环的环合
作者: Hong ZY(洪章勇) ; Xu XX(许杏祥)
通讯作者: 许杏祥
刊名: Tetrahedron Lett.
发表日期: 2003-01-01
卷: 44, 期:3, 页:489-491
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机化学实验室
英文摘要: The dienophile unit of methyl isosartortuoate has been synthesized. The 14-membered carbocycle was constructed by a SmI^2-mediated intramolecular reformatsky reaction. The introduction of the oxox group at the γ-position of the α, β-unsaturated ester was achieved by rearrangement of and β,γ-epoxy ester.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24343
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Hong ZY,Xu XX. Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization[J]. Tetrahedron Lett.,2003,44(3):489-491.
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