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Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization
Alternative Title以扭曲肉芝甲酯亲双烯体的合成研究第二部分:二碘化钐参与的14元碳环的环合
Hong ZY(洪章勇); Xu XX(许杏祥)
2003-01-01
Source PublicationTetrahedron Lett.
ISSN0040-4039
Volume44Issue:3Pages:489-491
AbstractThe dienophile unit of methyl isosartortuoate has been synthesized. The 14-membered carbocycle was constructed by a SmI^2-mediated intramolecular reformatsky reaction. The introduction of the oxox group at the γ-position of the α, β-unsaturated ester was achieved by rearrangement of and β,γ-epoxy ester.
Subject Area天然产物有机化学
Department中国科学院上海有机化学研究所现代有机化学实验室
URL查看原文
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/24343
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorXu XX(许杏祥)
Recommended Citation
GB/T 7714
Hong ZY,Xu XX. Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization[J]. Tetrahedron Lett.,2003,44(3):489-491.
APA 洪章勇,&许杏祥.(2003).Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization.Tetrahedron Lett.,44(3),489-491.
MLA 洪章勇,et al."Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI^2-mediated 14-membered carbocyclization".Tetrahedron Lett. 44.3(2003):489-491.
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