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学科主题: 金属有机化学
题名: Highly Efficient Synthesis of Multisubstituted 2-Acyl Furans via PIFA/I(2)-Mediated Oxidative Cycloisomerization of cis-2-En-4-yn-1-ols
其他题名: PIFA/I2促进的顺式烯炔醇的氧化环异构化反应: 多取代的2-酰基呋喃的合成
作者: Du XW(杜向伟) ; Chen HY(陈好益) ; Chen YF(陈宜峰) ; Chen JJ(陈敬金) ; Liu YH(刘元红)
通讯作者: 刘元红
刊名: Synlett
发表日期: 2011-01-01
期: 7, 页:1010-1014
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A novel oxidative cycloisomerization of cis-enynols has been developed using a combination of hypervalent iodine(III) reagent, molecular iodine, and a base. This method offers an efficient synthesis of 2-acyl furans with diverse substitution patterns in a regioselective manner under mild reaction conditions. A mechanistic proposal for these transformations involving alkyne activation by trifluoroacetylhypoiodite generated in situ is presented.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24305
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Du XW,Chen HY,Chen YF,et al. Highly Efficient Synthesis of Multisubstituted 2-Acyl Furans via PIFA/I(2)-Mediated Oxidative Cycloisomerization of cis-2-En-4-yn-1-ols[J]. Synlett,2011(7):1010-1014.
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