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学科主题: 金属有机化学
题名: Gold-Catalyzed Approach to Multisubstituted Fulvenes via Cycloisomerization of Furan/Ynes
其他题名: 金催化的经呋喃-炔的环异构化反应合成多取代的富烯
作者: Chen YF(陈宜峰) ; Liu YH(刘元红)
通讯作者: 刘元红
刊名: J. Org. Chem.
发表日期: 2011
卷: 76, 期:13, 页:5274-5282
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A new approach to functionalized fulvenes with an enone or enal moiety has been developed through gold-catalyzed intramolecular cycloisomerization of furan/ynes with a two-carbon tether in between the furan and the triple bond. The reaction proceeds with complete regioselectivity via a 6-endo-cyclization and high stereoselectivity. Moreover, the E- or Z-stereochemistry of the double bond in fulvene products can be easily controlled by performing the reaction in different solvents.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000291920900013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24299
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen YF,Liu YH. Gold-Catalyzed Approach to Multisubstituted Fulvenes via Cycloisomerization of Furan/Ynes[J]. J. Org. Chem.,2011,76(13):5274-5282.
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