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学科主题: 金属有机化学
题名: Stereoselective Synthesis of beta-Hydroxyallenes with Multiple Contiguous Stereogenic Centers via Aldehyde Addition to alpha-Alkenyl-Substituted Zirconacyclopentenes
其他题名: 通过醛对alpha-烯基取代的锆杂环戊烯的加成反应立体选择性地合成多手性的β-联烯醇类化合物
作者: Zhou YB(周叶兵) ; Chen JJ(陈敬金) ; Zhao CB(赵春波) ; Wang EJ(王二娟) ; Liu YH(刘元红) ; Li YX(李玉学)
通讯作者: 刘元红 ; 李玉学
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:15, 页:5326-5330
收录类别: SCI
部门归属: 上海有机所
英文摘要: A highly stereoselective methodology for the synthesis of beta-hydroxyallenes with multiple stereogenic centers including allenic axial chirality, as well as center chirality, via addition of alpha-alkenylzirconacyclopentenes to aldehyde is described, Remarkably, the reaction occurs with completely different chemoselectivity in comparison with the usual alkyl- or aryl-substituted zirconacyclopentenes; that means, the C-C bond formation occurred selectively at the alkenylic carbon substituted with phenyl or alkyl group, while in the latter cases, insertion of aldehydes into the alkyl-zirconium bond to afford seven-membered oxazirconacycles has usually been observed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000268480300025
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24269
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhou YB,Chen JJ,Zhao CB,et al. Stereoselective Synthesis of beta-Hydroxyallenes with Multiple Contiguous Stereogenic Centers via Aldehyde Addition to alpha-Alkenyl-Substituted Zirconacyclopentenes[J]. J. Org. Chem.,2009,74(15):5326-5330.
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