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学科主题: 金属有机化学
题名: Iron-Catalyzed Cascade Arene-Aldehyde Addition/Cyclizations for the Highly Efficient Synthesis of Xanthenes and Its Analogous: Observation of a C-C Bond Cleavage in Indole-Based Triarylmethanes
其他题名: 铁催化的由芳基-醛加成反应以及环化的串联反应合成夹氧杂蒽及其类似物:含吲哚基团的三芳基甲烷的碳-碳键断裂反应研究
作者: Li HF(李鸿峰) ; Yang JY(杨静宇) ; Liu YH(刘元红) ; Li YZ(李艳忠)
通讯作者: 刘元红 ; 李艳忠
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:17, 页:6797-6801
收录类别: SCI
部门归属: 上海有机所; 华东师范大学
英文摘要: An efficient, general, and one-pot procedure for the synthesis of multisubstituted xanthene derivatives through Fe(III)-catalyzed reactions of 2-aryloxybenzaldehydes with electron-rich arenes has been developed. This method offers several advantages such as high selectivities, mild reaction conditions, and easily accessible starting materials. A mechanistic study revealed that a C-C bond cleavage of a triarylmethane intermediate might be involved in the domino process.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000269257800042
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24267
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li HF,Yang JY,Liu YH,et al. Iron-Catalyzed Cascade Arene-Aldehyde Addition/Cyclizations for the Highly Efficient Synthesis of Xanthenes and Its Analogous: Observation of a C-C Bond Cleavage in Indole-Based Triarylmethanes[J]. J. Org. Chem.,2009,74(17):6797-6801.
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