中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 有机化学
题名: A general and efficient synthesis of substituted fluorenes and heterocycle-fused indenes containing thiophene or indole rings utilizing a Suzuki-Miyaura coupling and acid-catalyzed Friedel-Crafts reactions as key steps
其他题名: 偶联及Friedel-Crafts反应作为关键步骤的芴及含有噻吩或吲哚的杂环并茚类化合物的普适性合成
作者: Li GJ(李贵杰) ; Wang EJ(王二娟) ; Chen HY(陈好益) ; Li HF(李宏峰) ; Liu YH(刘元红) ; Wang P(王鹏)
通讯作者: 刘元红
刊名: Tetrahedron
发表日期: 2008
卷: 64, 期:38, 页:9033-9043
收录类别: SCI
部门归属: 上海有机所; 俄亥俄州立大学(美国)
英文摘要: A general and efficient synthesis of fluorenes or heterocycle-fused indenes including 3-thia-cyclopenta[a]indenes, 9-thia-indenol[1,2-a]indenes, 5,6-dihydroindeno[2,1-b]indoles has been developed. This methodology is realized by a multistep protocol. involving first preparation of ortho-formylbiaryls through Suzuki-Miyaura Coupling of o-bromobenzaldehydes with arylboronic acids or the coupling of aryl halides with 2-formylbenzene boronic acid, this is followed by Grignard addition and Friedel-Crafts cyclization reactions catalyzed by Bronsted or Lewis acid to form the desired fluorene or indene rings. The method offers several advantages such as high yields, high selectivities, mild reaction conditions, easily accessible starting materials, and so on. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259045100002
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24259
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2008124.pdf(919KB)----开放获取--View Download

Recommended Citation:
Li GJ,Wang EJ,Chen HY,et al. A general and efficient synthesis of substituted fluorenes and heterocycle-fused indenes containing thiophene or indole rings utilizing a Suzuki-Miyaura coupling and acid-catalyzed Friedel-Crafts reactions as key steps[J]. Tetrahedron,2008,64(38):9033-9043.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[李贵杰]'s Articles
[王二娟]'s Articles
[陈好益]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[李贵杰]‘s Articles
[王二娟]‘s Articles
[陈好益]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2008124.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace