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学科主题: 金属有机化学
题名: New zirconium-mediated approach toward regio- and stereocontrolled synthesis of trans-enediynes
其他题名: 有机锆促进的新型反式烯二炔的高效合成法
作者: Liu YH(刘元红) ; Gao HJ(高红军)
通讯作者: 刘元红
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:2, 页:309-311
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The coupling reactions of alpha-alkynylated zirconacyclopentene based on 1,4-bis(trimethylsilyl)-1,3-butadiyne with unsaturated compounds are described, which provide an efficient, regio- and stereocontrollable synthesis of trans-enediynes in a one-pot procedure. An interesting alkynyl group shift from alpha- to beta-position of the zirconium center during the reaction was observed, which was accountable for the novel transformations to trans-enediynes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000234657900034
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24237
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu YH,Gao HJ. New zirconium-mediated approach toward regio- and stereocontrolled synthesis of trans-enediynes[J]. Org. Lett.,2006,8(2):309-311.
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