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学科主题: 金属有机化学
题名: SYNTHESIS OF (3-METHOXYPROPYL)-CYCLOPENTADIENYLTITANIUM AND ZIRCONIUM COMPLEXES
其他题名: SYNTHESIS OF (3-METHOXYPROPYL)-CYCLOPENTADIENYLTITANIUM AND ZIRCONIUM COMPLEXES
作者: Qian YL(钱延龙) ; Li GS(李贵生)
通讯作者: 钱延龙
刊名: Polyhedron
发表日期: 1993-01-01
卷: 12, 期:8, 页:967-970
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Four titanium and zirconium complexes of (3-methoxypropyl)cyclopentadienyl, Cp2'MCl2 (M = Ti, Zr), Cp'CpTiCl2 and Cp'Cp''TiCl2 (Cp = C5H5, Cp'= MeOCH2 CH2CH2C5H4, CP'' = MeOCH2CH2C5H4), have been synthesized in good yields by reacting the potassium salt Cp'K with MCl4 (M = Ti, Zr), CpTiCl3 and Cp''TiCl3, respectively. Their IR spectra show that the oxygen atom in the side-chain does not coordinate with the central metals, while mass specta imply the coordination of oxygen with the metals is possible, in particular in some low-valent species.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24185
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Qian YL,Li GS. SYNTHESIS OF (3-METHOXYPROPYL)-CYCLOPENTADIENYLTITANIUM AND ZIRCONIUM COMPLEXES[J]. Polyhedron,1993,12(8):967-970.
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