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学科主题: 氟化学
题名: Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines
其他题名: 利用α-一氟亚砜亚胺制备一氟环氧乙烷衍生物以及后续开环转化
作者: Zhang W(张伟) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: Adv. Synth. Catal.
发表日期: 2010
卷: 352, 期:16, 页:2799-2804
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Monofluorinated epoxides were successfully prepared through the O-cyclization reaction between alpha-fluorosulfoximines and ketones. The obtained fluoroepoxides were found to readily undergo an interesting ring-opening process (involving both a C-F bond cleavage and another C-F bond formation) in the presence of titanium tetrafluoride or pyridinium poly(hydrogen fluoride) to afford alpha-fluorinated ketones. The later process constitutes a formal catalytic 1,2-fluorine shift reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000284004200015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24065
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang W,Hu JB. Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines[J]. Adv. Synth. Catal.,2010,352(16):2799-2804.
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