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学科主题: 氟化学
题名: Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations
其他题名: 亲核-,自由基-,亲电-(苯磺酰)二氟甲基化反应
作者: Hu JB(胡金波)
刊名: J. Fluor. Chem.
发表日期: 2009
卷: 130, 期:12, 页:1130-1139
收录类别: SCI
部门归属: 上海有机所
英文摘要: Selective incorporation of a fluoroalkyl moiety to modulate the properties of an organic molecule has become a frequently used strategy in life science- and materials science-related applications. In this context, selective introduction of a (phenylsulfonyl)difluoromethyl group (PhSO2CF2) into organic molecules has attracted much attention, since the PhSO2CF2 group can be regarded as a "chemical chameleon" that can be readily transformed into difluoromethyl (CF2H), difluoromethylene (–CF2–), and difluoromethylidene (55CF2) functionalities. This article overviews the recent development of (phenylsulfonyl)difluoromethylation reactions from 2003, including the nucleophilic (phenylsulfonyl) difluoromethylations with PhSO2CF2H, PhSO2CF2SiMe3 and PhSO2CF2Br reagents, free radical (phenylsulfonyl)difluoromethylations with PhSO2CF2I reagent, and electrophilic phenylsulfonyl)difluoromethylations with a hypervalent iodine(III)-CF2SO2Ph reagent.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000273133000010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24061
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Hu JB. Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations[J]. J. Fluor. Chem.,2009,130(12):1130-1139.
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