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Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations
其他题名亲核-,自由基-,亲电-(苯磺酰)二氟甲基化反应
Hu JB(胡金波)
2009
发表期刊J. Fluor. Chem.
ISSN0022-1139
卷号130期号:12页码:1130-1139
摘要Selective incorporation of a fluoroalkyl moiety to modulate the properties of an organic molecule has become a frequently used strategy in life science- and materials science-related applications. In this context, selective introduction of a (phenylsulfonyl)difluoromethyl group (PhSO2CF2) into organic molecules has attracted much attention, since the PhSO2CF2 group can be regarded as a "chemical chameleon" that can be readily transformed into difluoromethyl (CF2H), difluoromethylene (–CF2–), and difluoromethylidene (55CF2) functionalities. This article overviews the recent development of (phenylsulfonyl)difluoromethylation reactions from 2003, including the nucleophilic (phenylsulfonyl) difluoromethylations with PhSO2CF2H, PhSO2CF2SiMe3 and PhSO2CF2Br reagents, free radical (phenylsulfonyl)difluoromethylations with PhSO2CF2I reagent, and electrophilic phenylsulfonyl)difluoromethylations with a hypervalent iodine(III)-CF2SO2Ph reagent.
学科领域氟化学
部门归属上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000273133000010
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被引频次:85[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/24061
专题中科院有机氟化学重点实验室
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GB/T 7714
Hu JB. Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations[J]. J. Fluor. Chem.,2009,130(12):1130-1139.
APA 胡金波.(2009).Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations.J. Fluor. Chem.,130(12),1130-1139.
MLA 胡金波."Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations".J. Fluor. Chem. 130.12(2009):1130-1139.
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