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学科主题: 氟化学
题名: Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles
其他题名: 钯/醋酸-催化下利用一氟砜为亲核试剂对炔烃的氟烷基化反应
作者: Ni CF(倪传法) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: Tetrahedron Lett.
发表日期: 2009
卷: 50, 期:52, 页:7252-7255
收录类别: SCI
部门归属: 上海有机所
英文摘要: A facile palladium-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones in the presence of acetic acid has been achieved. By using different alpha-substituted fluoro(phenyisulfonyl)methane derivatives, a variety of allylated monofluoromethyl compounds were obtained with high regio- and stereoselectivity. Substrate scope and limitation were also examined, and it was found that the reaction was amenable to both 1-aryl-substituted propynes and 3-aryl-substituted propynyl ethers. (C) 2009 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000272221000006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24055
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Ni CF,Hu JB. Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles[J]. Tetrahedron Lett.,2009,50(52):7252-7255.
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